‘Jammed Networks’ of Nanotubes May Improve Flame-Retardancy

 
Post new topic   Reply to topic    Institute of Nanotechnology Forum Index -> Nanomaterial
View previous topic :: View next topic  
Author Message
grantnano
Site Admin


Joined: 03 Oct 2005
Posts: 432

PostPosted: Mon Dec 05, 2005 10:46 am    Post subject: ‘Jammed Networks’ of Nanotubes May Improve Flame-Retardancy Reply with quote

US Research Team Says ‘Jammed Networks’ of Carbon Nanotubes or Nanofibres May Improve the Flame-Retardancy of Products in Many Industry Areas

Jammed networks may cause upheaval in phone systems, but among wispy carbon nanotubes or nanofibers, a similar phenomenon may greatly improve flammability resistance and, perhaps, other properties in polymers, report researchers from the National Institute of Standards and Technology and the University of Pennsylvania.

Results achieved with two types of carbon nanotubes (single- and multi-walled) and with carbon nanofibers could help to eliminate trial-and-error in designing and producing nanocomposite materials with flame-retarding and other desired properties optimized for applications in areas ranging from packaging and electronics to construction and aerospace. The work appears in the December issue of Nature Materials.*

Nanoparticle fillers - especially clays - have been shown to reduce the flammability of plastics and other polymers. Previous work on these nanoclay flame retardants, says NIST fire researcher Takashi Kashiwagi, indicates that the additives are most effective when they migrate to form a continuous surface layer, creating a “heat shield” on top of the more flammable polymer matrix. The shield, he explains, suppresses the “vigorous bubbling” that can occur as the matrix breaks down.

However, if the plate-like nanoclay particles cluster into islands, heat escapes through cracks between them, compromising their performance as flame retardants.

To get around this problem, Kashiwagi and colleagues chose to investigate carbon nanotubes and nanofibers, which tend to be narrower and longer than nanoclays. These structures also have been shown to enhance strength, electrical conductivity and other material properties. The researchers reasoned that the extended, sinuous geometry of the tiny tubes and fibers might lend itself to forming a “continuous, network-structured protective layer” that is free of cracks.

When the researchers heated polymethyl methacrylate (PMMA) - a clear plastic - dispersed with carbon nanotubes or nanofibers, the material behaved like a gel. In a process dictated by their type, concentration and other factors, the nano additives dispersed throughout the PMMA matrix and eventually achieved a “mechanically stable network structure.” The researchers say the “jammed networks” formed as the nanocomposites underwent a change in identity, a transition from liquid to solid. The shift occurred at an optimal composition that the team called the “gel concentration.”

For single-walled carbon nanotubes - sheets of carbon atoms rolled into cylinders - top fire retardant performance was achieved when the fillers made up only 0.5 percent of the total mass of the material. For multi-walled carbon nanotubes, which are nested sets of carbon cylinders, the gel concentration was 1 percent. Both types of nanotubes have the potential to surpass nanoclays as effective fire retardants, says NIST materials scientist Jack Douglas.

Results suggest that the gel concentration also may mark the point at which other nanotube-enabled improvements in material properties are maximized, Douglas adds.

* T. Kashiwagi, F. Du, J.F. Douglas, K.I. Winey, R.H. Harris Jr., and J.R. Shields. Nanoparticle networks reduce the flammability of polymer nanocomposites. Nature Materials, December 2005, 928-933.

Source: National Institute of Standards and Technology (NIST).

URL: http://www.nist.gov/public_affairs/techbeat/tb2005_120105.htm#jammed

This story was posted on 2 December 2005.
Back to top
View user's profile Send private message
Display posts from previous:   
Post new topic   Reply to topic    Institute of Nanotechnology Forum Index -> Nanomaterial All times are GMT
Page 1 of 1
 

 
Jump to:  
You cannot post new topics in this forum
You cannot reply to topics in this forum
You cannot edit your posts in this forum
You cannot delete your posts in this forum
You cannot vote in polls in this forum


Powered by phpBB © 2001, 2002 phpBB Group